Advances in Organometallic Chemistry Volume 65 1st Edition by Pedro Perez ISBN 0128206918 9780128206911

Chapter One: Ion Pairing in Transition Metal Catalyzed Olefin Polymerization

• Abstract

• 1. Introduction

• 2. Activation and Activators: An Overview

• 3. NMR Spectroscopic Techniques

• 4. General Features of the Interionic Structure and Self-Aggregation Tendency of Ion Pairs (IPs)

• 5. Structure/Activity Relationships

• 6. In Situ Ligand Modifications, Deactivation Pathways, and Unusual Interionic Structures

• 7. Conclusions

• Acknowledgments

Chapter Two: Recent Advances in the Chemistry of Group 9—Pincer Organometallics

• Abstract

• 1. Introduction and Scope

• 2. Metal Oxidation States, Coordination Geometries, and Spin States

• 3. Functional Pincers

• 4. Concluding Remarks

• Acknowledgments

Chapter Three: Synthesis of Nitrogen-Containing Molecules via Transition Metal-Catalyzed Reactions on Isoxazoles, Anthranils, and Benzoisoxazoles

• Abstract

• 1. Introduction

• 2. Catalytic Reactions with Alkynes

• 3. Annulation of Anthranils with Alkynes or Allenes

• 4. Catalytic Reactions with Metal Carbenes

• 5. Catalytic Aryl CH Functionalization

• 6. Conclusion

• Acknowledgments

Chapter Four: Metal-Carbonyl Promoted Multicomponent Coupling of Alkynes for the Synthesis of Heterocyclic Compounds

• Abstract

• 1. Introduction

• 2. Oxygen-Based Heterocycles

• 3. Nitrogen-Based Heterocycles

• 4. Oxygen-Nitrogen-Based Heterocycles

• 5. Sulfur-Based Heterocycles

• 6. Phosphorous-Based Heterocycles

• 7. Inorganic Heterocycles

• 8. Metal-Carbonyls in Natural Product Synthesis

• 9. Conclusions