Contemporary Carbene Chemistry 1st Edition by Robert A Moss,Michael P Doyle ISBN 1118237951 9781118237953

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ISBN 10: 1118237951 

ISBN 13: 9781118237953

Author: Robert A. Moss, Michael P. Doyle

Presents the most innovative results in carbene chemistry, setting the foundation for new discoveries and applications

The discovery of stable carbenes has reinvigorated carbene chemistry research, with investigators seeking to develop carbenes into new useful catalysts and ligands. Presenting the most innovative and promising areas of carbene research over the past decade, this book explores newly discovered structural, catalytic, and organometallic aspects of carbene chemistry, with an emphasis on new and emerging synthetic applications.

Contemporary Carbene Chemistry features contributions from an international team of pioneering carbene chemistry researchers. Collectively, these authors have highlighted the most interesting and promising areas of investigation in the field. The book is divided into two parts:

• Part 1, Properties and Reactions of Carbenes, explores new findings on carbene stability, acid-base behavior, and catalysis. Carbenic structure and reactivity are examined in chapters dedicated to stable carbenes, carbodicarbenes, carbenes as guests in supramolecular hosts, tunneling in carbene and oxacarbene reactions, and ultrafast kinetics of carbenes and their excited state precursors. Theoretical concerns are addressed in chapters on computational methods and dynamics applied to carbene reactions.
• Part 2, Metal Carbenes, is dedicated to the synthetic dimensions of carbenes, particularly the reactions and catalytic properties of metal carbenes. The authors discuss lithium, rhodium, ruthenium, chromium, molybdenum, tungsten, cobalt, and gold.

All the chapters conclude with a summary of the current situation, new challenges on the horizon, and promising new research directions. A list of key reviews and suggestions for further reading also accompanies every chapter.

Each volume of the Wiley Series on Reactive Intermediates in Chemistry and Biology focuses on a specific reactive intermediate, offering a broad range of perspectives from leading experts that sets the stage for new applications and further discoveries.

Table of contents:

 Part 1: Properties and Reactions of Carbenes
CHAPTER 1: Carbene Stability
CHAPTER 2: Stable Carbenes
CHAPTER 3: Acid–Base Chemistry of Carbenes
CHAPTER 4: Computational Methods for the Study of Carbenes and their Excited States
CHAPTER 5: Dynamics in Carbene Reactions
CHAPTER 6: Ultrafast Kinetics of Carbene Reactions
CHAPTER 7: Tunneling in the Reactions of Carbenes and Oxacarbenes
CHAPTER 8: Carbodicarbenes
CHAPTER 9: Catalytic Reactions with N-Mesityl-Substituted N-Heterocyclic Carbenes
CHAPTER 10: Supramolecular Carbene Chemistry
Part 2: Metal Carbenes
CHAPTER 11: Modern Lithium Carbenoid Chemistry
CHAPTER 12: Rhodium Carbenes
CHAPTER 13: Ruthenium Carbenes
CHAPTER 14: Nucleophilic Carbenes of the Chromium Triad
CHAPTER 15: Cobalt-Mediated Carbene Transfer Reactions
CHAPTER 16: Gold Carbenes
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