Green polymer chemistry biocatalysis and materials II 1st Edition Cheng 9780841228955

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• ISBN 13:  9780841228955
• Author: Cheng

Green polymer chemistry is a very active area of research that has attracted the attention of the scientific community and the public at large. Developments in this area are stimulated by health and environmental concerns, interest in sustainability, desire to decrease the dependence on petroleum, and opportunity to design and produce “green” products and processes. A large number of publications have appeared, and many new methodologies have been reported. In consideration of the rapid advances in this area, the editors organized an international symposium on “Green Polymer Chemistry: Biocatalysis and Biobased Materials” at the American Chemical Society (ACS) national meeting in Philadelphia, PA in August 2012. The symposium was very successful, with a total of 63 papers and active participation and discussions among the leading researchers. Whereas all aspects of Green Polymer Chemistry were covered, a particular emphasis was placed on biocatalysis and biobased materials. Biocatalysis involves the use of enzymes, microbes, and higher organisms to carry out chemical reactions. It provides exciting opportunities to manipulate polymer structures, to discover new reaction pathways, and to devise environmentally friendly processes. It also benefits from innovations in biotechnology which enables cheaper and improved enzymes to be made and customized polymeric materials to be produced in vivo using metabolic engineering. Biobased materials also represent an equally exciting opportunity that has found many industrial and medical applications. There is commonality with biocatalysis because many biobased products are biodegradable, where enzymes and/or microbes are involved.

Table of contents:

1. Green Polymer Chemistry: A Brief Review

2. Enzyme-Based Technologies: Perspectives and Opportunities

3. Lipase-Catalyzed Synthesis of Poly(amine-co-esters) and Poly(lactone-co-?-amino esters)

4. Metrology as a Tool To Understand Immobilized Enzyme Catalyzed Ring-Opening Polymerization

5. Syntheses and Characterization of Aliphatic Polyesters via Yarrowia lipolytica Lipase Biocatalysis

6. Microwave-Assisted Biocatalytic Polymerizations

7. Green Polymer Chemistry: Enzymatic Functionalization of Poly(ethylene glycol)s Under Solventless Conditions

8. Biocatalysis for Silicone-Based Copolymers

9. Comparison of Polyester-Degrading Cutinases from Genus Thermobifida

10. “Green” Synthesis of Bisphenol Polymers and Copolymers, Mediated by Supramolecular Complexes of Laccase and

11. Synthesis of New Polysaccharide Materials by Phosphorylase-Catalyzed Enzymatic ?-Glycosylations Using Polymeric

12. Biocatalytic ATRP: Controlled Radical Polymerizations Mediated by Enzymes

13. Microbial Plastic Factory: Synthesis and Properties of the New Lactate-Based Biopolymers

14. Synthesis of Poly-(R)-3 Hydroxyoctanoate (PHO) and Its Graphene Nanocomposites

15. Biosynthesis of Polyhydroxyalkanoate by a Marine Bacterium Vibrio sp. Strain Using Sugars, Plant Oil, and Unsaturated

16. PEGylated Antibodies and DNA in Organic Media and Genetic PEGylation

17. Effect of Polycondensation Conditions on Structure and Thermal Properties of Poly(caffeic acid)

18. Biodegradable Films and Foam of Poly(3-Hydroxybutyrate-co-3-hydroxyvalerate) Blended with Silk Fibroin

19. Synthesis and NMR Characterization of Hyperbranched Polyesters from Trimethylolpropane and Adipic Acid

20. Direct Fluorination of Poly(3-hydroxybutyrate-co)-hydroxyhexanoate

21. Biobased Industrial Products from Soybean Biorefinery

22. Applications of Common Beans in Food and Biobased Materials

23. Preparation and Characterization of Protein Isolate from Glandless and Glanded Cottonseed

24. Hydrogenated Cottonseed Oil as Raw Material for Biobased Materials

25. Lignin-Based Graft Copolymers via ATRP and Click Chemistry

26. Esterification of Xylan and Its Application

27. Converting Polysaccharides into High-Value Thermoplastic Materials

28. Use of Cotton Gin Trash and Compatibilizers in Polyethylene Composites

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