Ligand Design in Metal Chemistry Reactivity and Catalysis 1st Edition by Mark Stradiotto ISBN 9781118839836 1118839838

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ISBN 10:   1118839838

ISBN 13: 9781118839836

Author:  Mark Stradiotto

The design of ancillary ligands used to modify the structural and reactivity properties of metal complexes has evolved into a rapidly expanding sub-discipline in inorganic and organometallic chemistry. Ancillary ligand design has figured directly in the discovery of new bonding motifs and stoichiometric reactivity, as well as in the development of new catalytic protocols that have had widespread positive impact on chemical synthesis on benchtop and industrial scales.

Ligand Design in Metal Chemistry presents a collection of cutting-edge contributions from leaders in the field of ligand design, encompassing a broad spectrum of ancillary ligand classes and reactivity applications. Topics covered include:

• Key concepts in ligand design
• Redox non-innocent ligands
• Ligands for selective alkene metathesis
• Ligands in cross-coupling
• Ligand design in polymerization
• Ligand design in modern lanthanide chemistry
• Cooperative metal-ligand reactivity
• P,N Ligands for enantioselective hydrogenation
• Spiro-cyclic ligands in asymmetric catalysis

This book will be a valuable reference for academic researchers and industry practitioners working in the field of ligand design, as well as those who work in the many areas in which the impact of ancillary ligand design has proven significant, for example synthetic organic chemistry, catalysis, medicinal chemistry,  polymer science and materials chemistry.

Table of contents: 

CHAPTER 1: Key Concepts in Ligand Design: An Introduction
CHAPTER 2: Catalyst Structure and Cis–Trans Selectivity in Ruthenium-based Olefin Metathesis
CHAPTER 3: Ligands for Iridium-catalyzed Asymmetric Hydrogenation of Challenging Substrates
CHAPTER 4: Spiro Ligands for Asymmetric Catalysis
CHAPTER 5: Application of Sterically Demanding Phosphine Ligands in Palladium-Catalyzed Cross-Coupling leading to C(sp 2)─E Bond Formation
CHAPTER 6: Pd-N-Heterocyclic Carbene Complexes in Cross-Coupling Applications
CHAPTER 7: Redox Non-innocent Ligands: Reactivity and Catalysis
CHAPTER 8: Ligands for Iron-based Homogeneous Catalysts for the Asymmetric Hydrogenation of Ketones and Imines
CHAPTER 9: Ambiphilic Ligands: Unusual Coordination and Reactivity Arising from Lewis Acid Moieties
CHAPTER 10: Ligand Design in Enantioselective Ring-opening Polymerization of Lactide
CHAPTER 11: Modern Applications of Trispyrazolylborate Ligands in Coinage Metal Catalysis
CHAPTER 12: Ligand Design in Modern Lanthanide Chemistry
CHAPTER 13: Tight Bite Angle N,O-Chelates. Amidates, Ureates and Beyond

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Tags: Mark Stradiotto, Ligand Design, Metal Chemistry, Reactivity, Catalysis