Liquid Phase Aerobic Oxidation Catalysis Industrial Applications and Academic Perspectives 1st Edition by Shannon S Stahl,Paul L Alsters ISBN 3527337814 978-3527337811

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Product details:

ISBN 10: 3527337814

ISBN 13: 978-3527337811

Author: Shannon S. Stahl, Paul L. Alsters

 The first book to place recent academic developments within the context of real life industrial applications, this is a timely overview of the field of aerobic oxidation reactions in the liquid phase that also illuminates the key challenges that lie ahead.
As such, it covers both homogeneous as well as heterogeneous chemocatalysis and biocatalysis, along with examples taken from various industries: bulk chemicals and monomers, specialty chemicals, flavors and fragrances, vitamins, and pharmaceuticals. One chapter is devoted to reactor concepts and engineering aspects of these methods, while another deals with the relevance of aerobic oxidation catalysis for the conversion of renewable feedstock.
With chapters written by a team of academic and industrial researchers, this is a valuable reference for synthetic and catalytic chemists at universities as well as those working in the pharmaceutical and fine chemical industries seeking a better understanding of these reactions and how to design large scale processes based on this technology.

Table of contents: 

Part I: Radical Chain Aerobic Oxidation

1. Overview of Radical Chain Oxidation Chemistry

2. Noncatalyzed Radical Chain Oxidation: Cumene Hydroperoxide

3. Cyclohexane Oxidation: History of Transition from Catalyzed to Noncatalyzed

4. Oxidation of para-Xylene to Terephthalic Acid Using Co–Mn–Br Catalyst

Part II: Cu-Catalyzed Aerobic Oxidation

5. Cu-Catalyzed Aerobic Oxidation: Overview and New Developments

6. Copper-Catalyzed Aerobic Alcohol Oxidation

7. Phenol Oxidations

Part III: Pd-Catalyzed Aerobic Oxidation

8. Pd-Catalyzed Aerobic Oxidation Reactions: Industrial Applications and New Developments

9. Acetaldehyde from Ethylene and Related Wacker-Type Reactions

10. 1,4-Butanediol from 1,3-Butadiene

11. Mitsubishi Chemicals Liquid Phase Palladium-Catalyzed Oxidation Technology

12. Oxidative Carbonylation: Diphenyl Carbonate

13. Aerobic Oxidative Esterification of Aldehydes with Alcohols

Part IV: Organocatalytic Aerobic Oxidation

14. Quinones in Hydrogen Peroxide Synthesis and Catalytic Aerobic Oxidation Reactions

15. NOx Cocatalysts for Aerobic Oxidation Reactions

16. N-Hydroxyphthalimide (NHPI)-Organocatalyzed Aerobic Oxidations

17. Carbon Materials as Nonmetal Catalysts for Aerobic Oxidations

Part V: Biocatalytic Aerobic Oxidation

18. Enzyme Catalysis: Biocatalysis and Aerobic Oxidations for Pharmaceutical Syntheses

Part VI: Oxidative Conversion of Renewable Feedstocks

19. From Terephthalic Acid to 2,5-Furandicarboxylic Acid

20. Azelaic Acid from Vegetable Feedstock

21. Oxidative Conversion of Renewable Feedstock: Carbohydrate Oxidation

Part VII: Aerobic Oxidation with Singlet Oxygen

22. Industrial Prospects for Singlet Oxygenation of Organic Compounds

Part VIII: Reactor Concepts for Liquid Phase Aerobic Oxidation

23. Reactor Concepts for Aerobic Liquid Phase Oxidation

Index

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Tags: Shannon S Stahl, Paul L Alsters, Liquid Phase Aerobic, Oxidation Catalysis Industrial, Applications and Academic Perspectives