Pericyclic reactions : a mechanistic and problem solving approach 1st Edition Kumar 0128036699 9780128036402 9780128036693

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Product details:

• ISBN 10: 0128036699 
• ISBN 13: 9780128036402, 9780128036693 
• Author: Kumar

Pericyclic Reactions: A Mechanistic and Problem-Solving Approach provides complete and systematic coverage of pericyclic reactions for researchers and graduate students in organic chemistry and pharmacy programs. Drawing from their cumulative years of teaching in the area, the authors use a clear, problem-solving approach, supplemented with colorful figures and illustrative examples.

Written in an accessible and engaging manner, this book covers electrocyclic reactions, sigmatropic reactions, cycloaddition reactions, 1,3-dipolar reactions, group transfer, and ene reactions. It offers an in-depth study of the basic principles of these topics, and devotes equal time to problems and their solutions to further explore those principles and aid reader understanding. Additional practice problems are provided for further study and course use.

Table of contents:

Chapter 1. Pericyclic Reactions and Molecular Orbital Symmetry

1.1. Classification of Pericyclic Reactions

1.2. Molecular Orbitals of Alkenes and Conjugated Polyene Systems

1.3. Molecular Orbitals of Conjugated Ions or Radicals

1.4. Symmetry Properties of π or σ-Molecular Orbitals

1.5. Analysis of Pericyclic Reactions

Chapter 2. Electrocyclic Reactions

2.1. Conrotatory and Disrotatory Modes

2.2. Stereochemistry of Electrocyclic Reactions

2.3. Selection Rules for Electrocyclic Reactions

2.4. Analysis of Electrocyclic Reactions

2.5. Electrocyclic Reactions of Ionic Species

Chapter 3. Sigmatropic Rearrangements

3.1. Suprafacial and Antarafacial Processes

3.2. Analysis of Sigmatropic Rearrangements of Hydrogen

3.3. Analysis of Sigmatropic Rearrangements of Alkyl Group

3.4. [3,3] Sigmatropic Rearrangements

3.5. [5,5] Sigmatropic Shift

3.6. [2,3] Sigmatropic Rearrangements

3.7. Peripatetic Cyclopropane Bridge: Walk Rearrangements

3.8. Sigmatropic Rearrangements Involving Ionic Transition States

Chapter 4. Cycloaddition Reactions

4.1. Stereochemical Modes of Cycloaddition

4.2. Feasibility of Cycloaddition Reactions

4.3. [2 + 2] Cycloadditions

4.4. [4 + 2] Cycloadditions

4.5. Higher Cycloadditions

4.6. Cycloaddition of Multiple Components

Chapter 5. Cheletropic Reactions and 1,3-Dipolar Cycloadditions

5.1. Cheletropic Reactions

5.2. 1,3-Dipolar Cycloadditions

Chapter 6. Group Transfer, Elimination, and Related Reactions

6.1. Group Transfer Reactions

6.2. Elimination Reactions

6.3. Dyotropic Rearrangements

6.4. Ene Reactions

6.5. β-Eliminations Involving Cyclic Transition Structures

Chapter 7. Unsolved Problems

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