Polymers from plant oils 2nd Edition by Alessandro Gandini, Talita M Lacerda ISBN 1119555795 978-1119555797

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Product details:

ISBN 10: 1119555795

ISBN 13: 978-1119555797 

Author: Alessandro Gandini, Talita M. Lacerda

Unique state-of-the-art book on an important topic in renewable materials

The purpose of this monograph is to provide a thorough outlook on the topic related to the synthesis and characterization of original macromolecular materials derived from plant oils, an important part of the broader steadily growing discipline of polymers from renewable resources. The interest in vegetable oils as sources of biodiesel and materials has witnessed a remarkable growth of scientific and industrial interest since the beginning of the third millennium responding to the pressing drive to implement sustainability in the energy and materials sectors.

The book highlights the most relevant strategies being pursued to elaborate polymers derived from a variety of common oils, by direct activation or through chemical modifications yielding novel monomers. Because glycerol is the main byproduct of biodiesel production, it is treated here as the other logical source of macromolecular synthesis. Each of the different approaches is illustrated by an introductory layout of the underlying chemical mechanisms, followed by examples of notable achievements in terms of the properties and potential applications of the ensuing materials, which span a wide range of structures and performances. In particular, original pathways involving click-chemistry reactions as thiol-ene and Diels-Alder couplings and metathesis polymerizations are discussed and shown to reflect the involvement of a growing number of research programs worldwide.

Table of contents:

1 Introduction
1.1 Setting the Stage
References

2 Basic Chemical Notions
2.1 Drying Mechanism
2.2 Reactive Sites
2.2.1 Reactions of the Ester Group
2.2.2 Reactions of Unsaturated Bonds
References

3 Polymerisation of Pristine Oils and their Fatty Acids
3.1 Polymerisation of Unsaturated Oils and Fatty Acids
3.2 Specific Case of Castor Oil
References

4 Monomers and Polymers from Chemically Modified Plant Oils and their Fatty Acids
4.1 Epoxidised Structures
4.1.1 Direct Polymerisation
4.1.2 Reactions with Amines and Anhydrides
4.1.3 Acrylation Reactions
4.2 Polyol Structures for Polyurethanes
4.3 Polyisocyanates for Polyurethanes
4.4 Polyether and Polyester Diols for Thermoplastic Polyurethanes
4.5 Diols and Diacids for Linear Polyesters
4.6 Monomers for Linear Polyamides and Polycarbonates
4.7 Vinyl, Acrylic and Other Monomers for Linear Chain-growth Polymerisation
4.8 Monomers for Other, Less Common Linear Polymers
4.9 Special Cases of Castor Oil and Ricinoleic Acid
4.10 Special Case of Glycerol
References

5 Metathesis Reactions Applied to Plant Oils and Polymers Derived from the Ensuing Products
5.1 General Considerations
5.2 Metathesis Reactions as Tools for the Synthesis of Monomers and Polymers Derived from Vegetable Oils
5.2.1 Metathesis Reactions for Monomer Synthesis
5.2.2 Olefin Metathesis Applied to Polymer Synthesis
5.2.2.1 Acyclic Diene Metathesis Polymerisation
5.2.2.2 Acyclic Triene Metathesis Polymerisation
5.2.2.3 Ring-opening Metathesis Polymerisation
5.2.2.4 Special Cases of Acetal Metathesis Polymerisation and Alternating Diene Metathesis Polymerisation
References

6 Thiol-ene and Thiol-yne Reactions for the Transformation of Oleochemicals into Monomers and Polymers
6.1 General Considerations
6.2 Thiol-ene Reaction as a Tool for the Synthesis of Monomers and Polymers Derived from Vegetable Oils
6.2.1 Thiol-ene Reactions for Monomer Synthesis
6.2.2 Thiol-ene Reactions Applied to Polymer Synthesis
6.2.3 Thiol-ene Reactions for Chemical Modifications after Polymerisation
6.3 Thiol-yne Reaction as a Tool for the Synthesis of Monomers and Polymers Derived from Vegetable Oils
6.4 Final Considerations
References

7 Diels–Alder Reactions and Polycondensations Applied to Vegetable Oils and their Derivatives

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Tags: Alessandro Gandini, Polymers, Plant, Oils